Since 2000, a Thermal Ionisation Mass Spectrometer (Thermo ScientificTM Triton TI® Mass Spectrometer) and a clean laboratory are operating at the Istituto Nazionale di Geofisica e Vulcanologia (INGV), Sezione di Napoli, Osservatorio Vesuviano (OV) to measure strontium (Sr) and neodymium (Nd) isotope compositions of volcanic products for scientific purposes. In 2014 particular attention has been dedicated to set up the analytical procedure for extracting Sr and Nd and measuring their isotope compositions from groundwater and mineral water, due to its growing interest on environmental topics. Strontium is considered a trace element and Sr2+ preferentially substitutes for Ca2+ in most rock types since it geochemically behaves like calcium. Groundwater is enriched in Sr during water-rock...